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Activated carbon
[CAS 64365-11-3]

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Identification
ClassificationCatalysts and additives >> Molecular sieve
NameActivated carbon
SynonymsActivated charcoal
Molecular FormulaC
Molecular Weight12.01
CAS Registry Number64365-11-3
EC Number264-846-4
SMILES[C]
Safety Data
Hazard Symbolssymbol   GHS02 Warning  Details
Risk StatementsH252  Details
Safety StatementsP235-P280-P407-P410-P413-P420  Details
Hazard Classification
up    Details
HazardClassCategory CodeHazard Statement
Self-heating substances or mixturesSelf-heat.2H252
SDSAvailable
up chemBlink Chemical Story
Activated carbon is not defined by one molecular structure. It is a porous carbon material whose performance comes from an enormous internal surface created by carbonization and activation. That distinction is important for CAS 64365-11-3: a drawing of a single carbon molecule would be misleading. Activated carbon is better understood as an engineered landscape of pores and surface functional groups.

Charcoal has been used for purification for centuries, but modern activated carbon emerged when chemists learned to create controlled porosity. A carbon-rich precursor such as wood, coconut shell, coal, or other biomass is first converted to char. Activation with steam, carbon dioxide, or chemical agents then removes selected carbon atoms and opens a hierarchy of micro-, meso-, and larger pores. Much of the useful surface is hidden inside pores only nanometers wide.

Adsorption occurs because molecules are stabilized on these internal surfaces by dispersion forces, hydrophobic interactions, electrostatics, and sometimes specific surface chemistry. Micropores provide enormous area and strong adsorption potential for small molecules; larger pores help transport adsorbates into the particle. Surface oxygen groups can change acidity, polarity, and affinity for ions. Consequently, surface area alone does not predict every application. Pore-size distribution and surface chemistry must match the contaminant.

This is why activated carbon appears in seemingly unrelated technologies: drinking-water treatment, air purification, solvent recovery, food decolorization, gas masks, gold recovery, and emergency treatment of some poisonings. In each case the same general principle is used - concentrate selected molecules from a fluid onto a solid surface - but the optimal carbon may be very different. A vapor-phase adsorbent, a powdered drinking-water carbon, and a medical activated charcoal are not interchangeable simply because all are black carbon powders.

Regeneration is another important part of the activated-carbon story. Adsorption capacity is finite, so industrial granular carbon is often thermally reactivated rather than discarded after one use. Heating under controlled conditions can desorb or destroy captured organics and reopen pores, although some carbon is lost and the pore structure may change each cycle. This makes activated carbon not only an adsorbent but part of a materials-management loop. Whether regeneration is practical depends on contaminant type, carbon form, transport, energy use, and purity requirements.

Activated carbon matters because it turns absence into function. Its most valuable feature is not the carbon framework alone but the network of empty space created inside it. By controlling how carbon is removed during activation, manufacturers create surfaces that can capture other molecules. It is a striking materials-science lesson: sometimes the useful part of a solid is the void structure engineered within it.

References:

1. Blaker C et al. ChemBioEng Reviews. 2019;6:119-138. DOI: 10.1002/cben.201900008.

2. Marsh H, Rodriguez-Reinoso F. Activated Carbon. Elsevier, 2006.

3. Recent reviews of activated carbon in water and emerging-pollutant remediation.

4. USP and toxicological literature for medicinal activated charcoal.

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